Activator Generated by Electron Transfer (AGET) ATRP
AGET ATRP has a significant advantage over " reverse" ATRP and SR&NI ATRP, described above, because it provides a route for synthesizing pure tele-functional polymeric materials of any desired architecture (1-3,5) while employing active catalyst complexes.
Immersion in Advanced Oxidation Water Followed by AGET-ATRP …
2023年6月27日 · A facile surface modification method in which membranes were immersed in advanced oxidation water (ozone and hydrogen peroxide co-dissolved in water) followed by activator generated by electron transfer-atom transfer radical polymerization (AGET-ATRP) was developed to obtain low-fouling membranes.
Aqueous ARGET ATRP | Macromolecules - ACS Publications
2012年8月2日 · Activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) was successfully implemented in aqueous media for the first time.
Uniform polymer–protein conjugate by aqueous AGET ATRP …
2011年5月1日 · In situ aqueous activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP) in air, using an enzyme as a macroinitiator, has been proposed to prepare uniform polymer–protein conjugates with improved stability under adverse conditions.
ARGET ATRP of Methyl Acrylate and Methyl ... - ACS Publications
2022年9月2日 · Diazocine-functionalized initiators for atom transfer radical polymerization (ATRP) were synthesized and tested for their efficiency in controlled radical polymerizations of methyl acrylate and methacrylate under reaction conditions …
According to the definition of atom transfer radical addition (ATRA) [1, 2], i.e., the origin of atom transfer radical polymerization (ATRP), it is a radical polymerization that proceeds via the transfer of one atom (X) from a polymer terminus (R1–X) to another growing polymer radical species (R2).
K. Min, W. Jakubowski and K. Matyjaszewski, “AGET ATRP in the …
ABSTRACT: The atom transfer radical polymerization on the mechanism of activator generation by electron transfer (AGET ATRP) of methyl methacrylate (MMA) in N,N-dimethylformamide (DMF) in the presence of the catalytic systems, namely, CCl4-FeCl3-1-acetyl-2-phenylhydrazine (APH) and CCl4-FeCl3-ascorbic acid (AA) is reported.
Given the gigantic harmfulness of bisphenol A (BPA), a novel and ultrasensitive aptasensor, which employs the truncated BPA aptamer, click chemistry, and activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP), was developed herein for the quantitative determination of BPA.
- [PDF]
www.mcp-journal.de …
From this surface, SI-AGET ATRP of acrylamide monomers is performed. The resulting AC-PAM is characterized by FTIR, XPS, TGA, and BET analysis. Additionally, the grafted polymer is cleaved from the surface of AC and its molecular weight distribution is measured by SEC.
Among the developed ATRP techniques, the AGET ATRP seems the most suitable one for production of required acry-lonitrile copolymers due to its high efficiency and low con-centrations of used catalyst [10, 25].